Introduction to transition metals and the d-block elements

Introduction to transition metals and the d-block elements

Lessons

In this lesson, we will learn:

  • The definition of a transition metal as distinguished from a d-block element.
  • The general properties of d-block and transition metal elements.
  • How to write electron configurations for the transition metal elements and their common ions.
Notes:

  • Until now we have only really looked at the groups of elements around the edges of the periodic table, like the halogens, noble gases and alkali metals. These groups have very distinct properties that make them a bit easier to study and learn about.
    This module is all about the transition metals and the d-block, which is right in the middle of the periodic table!

  • Just like the halogens and the alkali metals, there are properties and features that you expect to see in the d-block elements. It is not always as clear-cut as the other groups, but generally they are:
    • Variable oxidation states, such as Fe (II) and Fe (III)
    • Coloured compounds, such as copper (II) or chromium (VI)
    • Ability to form complex ions.

  • The biggest distinction to make is the difference between a d-block element and a transition metal – they are not the same definition!
    • A d-block element is any element found in the central d-block of the periodic table – this is simple enough. If its ground-state (the neutral atom) electron configuration ends with a d-subshell (such as 3d1-10), it is a d-block element.
    • A transition metal is any d-block element with a ground-state and at least one stable ion with a PARTIALLY FILLED d-subshell.
    So, all transition metals are d-block elements, but not all d-block elements are transition metals.

  • The difference is easiest to explain with examples using electron configuration.
    • Scandium is a d-block element but IS NOT a transition metal. This is because, despite its neutral atom having an outer shell configuration of 4s2 3d1, its only stable ion is Sc3+, which removes all three of those outer shell electrons, leaving it with an [Ar] 4s0 3d0 or just [Ar] electron configuration. This is an empty d-subshell, not a partially filled one! Therefore, scandium does not count.

    • Zinc IS NOT a transition metal. Again, the neutral atom has an outer shell configuration ending with the d-subshell (3d10), but its only stable ion is Zn2+, which has the outer shell configuration 4s0 3d10. This is completely filled, not partially! Therefore, zinc is not a transition metal.

    • Iron IS a transition metal. Its ground-state electron configuration is 4s2 3d6, and it forms two stable ions:
      • Fe2+ with the configuration 4s0 3d6
      • Fe3+ with the configuration 4s0 3d5.
      The ground state and both these stable ions satisfy the partially-filled criteria, so iron counts as a transition metal in the d-block.

  • To easily distinguish transition metals in the d-block, you need to know the electron configurations for ground-state d-block elements and their common ions. There are a few guidelines to this:
    • When filling subshells, the 4s subshell is filled first, then 3d. The 3d sub-shell is made up of 5 orbitals, for a total of 10 electrons. Like in the p-subshell, the electrons fill up a separate orbital first before pairing up.
      • For example, reading across the beginning 1st row of d-block elements we see the following pattern:

    • When 1strow transition metals become ions, the 4s2 electrons are removed first.
      • For example, Ti2+ has an ion electron configuration of [Ar] 4s0 3d2, as the 4s electrons are removed first.
      This is why the +2 oxidation state is common for transition metals. If a transition metal can form an M2+ ion, it is probably by removing the 4s2 electrons, without touching the 3d electrons.

    • Many ions have electron configurations ‘settled’ on a half-filled or completely empty d-subshell. If you have a metal ion of an unusual charge/oxidation state and need to suggest the configuration, try to ‘remove’ electrons from the 3d subshell until it is half or completely empty.
      • For example, after Fe (II), iron’s other main oxidation state is Fe (III), which removes the one paired electron of its 3d6 electrons to give [Ar] 4s0 3d5 as its ion electron configuration.
      • Manganese (VII) is possible because the ground state of Mn is 4s2 3d5. Manganese loses control of these seven when it becomes Mn (VII), the type used in a lot of redox reactions.

    • Chromium and copper are ‘special cases’ with their electron configurations. The ground-state configurations of chromium and copper respectively show a half-filled and completely-filled 3d subshell. They get this from the paired 4s subshell which becomes half-filled itself.

    • The reasons for this are complex; it is just easier to remember that these particular two elements are more stable with a 4s1 3d5 or 4s1 3d10 ground state.
  • Introduction
    Introduction to transition metals.
    a)
    General properties of the d-block.

    b)
    Definitions of transition metals and d-block elements.

    c)
    Electron configurations for d-block elements.


  • 1.
    Identify and write the electron configuration for the following d-block metals and their ions.
    a)
    Write the electron configurations for the following species:
    1. V2+
    2. Fe3+
    3. Cu+

    b)
    A metal ion has 22 protons and 20 electrons. Give the chemical symbol for it and write its electron configuration.