Introduction to organic chemistry - Basic Organic Chemistry

Introduction to organic chemistry

Lessons

Notes:
In this lesson, we will learn:
  • How organic chemistry began and how it got its name.
  • The reason that carbon's chemistry is studied much more than the chemistry of other elements.
  • The basic rules of naming simple organic compounds.
  • The different ways to draw and represent organic compounds and their features.

Notes:
  • Organic chemistry is all about carbon. Any chemical compound that contains carbon atoms can be called an organic compound but it usually means compounds with a carbon chain of some sort.
    The earliest organic chemistry started with chemicals found from living organisms like trees, other plants and animals.
    Some of the most important molecules in living organisms are carbon compounds:
    • Amino acids that combine to make the proteins in our body.
    • Nucleotides that combine to make the DNA in our cells.
    • Glucose that breaks down in respiration, producing the energy for all living processes.
    It is here that it gets its organic name from; carbon is the element of life on Earth.
  • Carbon atoms can make four separate bonds with any other atom(s), including other carbon atoms. This flexibility opens up an incredibly large number of types of bonding to different atoms. This is why there are around ten million known organic compounds and why organic chemistry has grown so large to become a subject in its own right.
  • Aside from living organisms, organic molecules have a wide range of uses in our day to day lives, with most being products of crude oil and the petroleum industry. Some organic chemicals from crude oil are:
    • Gasoline/petrol, fuel for cars.
    • Kerosene, fuel for aircraft.
    • Refinery gases used as fuels and as resources to make plastics.
    • Bitumen, used to tar roads.
    • 'Naphtha' which is a mix of organic compounds that are used to make many different substances.
    The pharmaceutical industry uses organic compounds taken from crude oil and makes medicinal organic compounds that treat many conditions, such as:
    • Atorvastatin, heart disease medication.
    • Humira, a medication for many autoimmune (the body attacking itself) diseases.
    • Prozac, an antidepressant.
    • Salbutamol, anti-asthma medication.
    Organic means carbon-based but it is also a word sometimes used in a positive light to mean natural and not artificial. This ignores that all man-made chemicals were man-made using naturally occurring substances found on Earth.
    To a chemist, calling a chemical substance natural or artificial/man-made is totally meaningless; is a treehouse unnatural? 'Natural' or 'unnatural' is a useless comment because it tell us absolutely nothing about a chemical's properties. There are toxic natural substances and safe, beneficial ones. The same goes with synthetics.
  • There are so many organic compounds that they are divided into categories depending on what atoms or types of bonds they contain. Amongst the simplest and most important, compounds containing only carbon and hydrogen are called hydrocarbons.
  • There is a systematic way of naming organic compounds. The two most important, basic rules are below:
    • Identify the longest carbon chain in the compound. This is the core of the compound name. Depending on the carbon chain length, the following names are assigned. The table below summarizes them.
    • Carbon chain length:

      Root name:

      1

      Meth-

      2

      Eth-

      3

      Prop-

      4

      But-

      5

      Pent-

      6

      Hex-

      7

      Hept-

      8

      Oct-


    • Identify the functional group(s) in the compound. This will give you the suffix (end part) of the name. A few basic examples (which we'll study in detail later) are in the table below.
    • Functional group

      Suffix

      Alkane

      -ane

      Alkene

      -ene

      Alkyne

      -yne

      Alcohol

      -ol


    • Combining these two parts will give you the name of unbranched organic compounds:
      • e.g. hexane (6 carbon chain, alkane), butene (4 carbon chain, alkene), ethyne (2 carbon chain, alkyne). We will learn to identify these later.
      • butene (4 carbon chain, alkene),
      • ethyne (2 carbon chain, alkyne).
      • We will identify, draw and learn the properties of these later.
  • When studying organic compounds, there are many ways to represent a chemical compound that we are talking about. Some are simpler than others, and some are more appropriate in certain situations.
    • We already know the molecular formula, which shows the chemical symbols of the atoms in the molecule and how many of these atoms there are. For example CH4 is a compound which has one carbon atom (symbol C) and four hydrogen atoms (symbol H) in each molecule.
    • The empirical formula is a shortened version of the molecular formula which shows the smallest whole-number ratio of the molecular formula. For C2H6, the empirical formula would be CH3.
    • For organic compounds we can also use the condensed formula – this is used to show the chain of carbon atoms in the compound. For example C5H12 can be written as CH3-CH2-CH2-CH2-CH3 to show the 5 carbon chain in the molecule.
    • You could also use the structural/displayed formula, which shows all the bonds between all atoms in the molecule.
    • The structural formula can be simplified by using skeletal formula – this is where a carbon atom is shown as a joint in a zig-zag chain which is the carbon backbone of the organic compound being represented. In skeletal formula, hydrogen atoms are 'implicit' meaning they are present but not shown in the representation. The 'ends' of the zig zag chains count as carbon atoms as well.
      We will build on skeletal formula and drawing molecules later on.
      • Two examples of compounds shown with each of these formulae are shown below:
    • Hexane in different formula




      Butane in different formula


    • Intro Lesson
      Organic chemistry - Introduction
    • 2.
      Discuss the uses and benefits of using different chemical formulae methods.
      Codeine is a drug used to treat headaches and other forms of pain. It has a molecular formula of C18_{18}H21_{21}NO3_3.
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    Introduction to organic chemistry

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